I have always understood that pitch and tar were about the same, rendered from fat pine, or "lighterd knots," as we call them here in the south. This "fat wood" is the heartwood of dead pine trees. Pitch and tar are both solid black in color, sticky and messy, with a pretty low melting point, although it will eventually harden with exposure. Pine tar is still widely used in equine veterinary wound treatment. If you search for pine tar on the web, you'll probably find it for sale in a can with a picture of a horse on it. Pine tar was also used as a lubricant on wagon axles. The friction of the rolling wheel would heat it enough to virtually liquify it, but it would hold up better than lard or tallow for this application.
Rosin is the purified and hardened sap, usually collected from live pine trees. It is not the same as pitch or tar. It is a pale amber color in its purified form, and in fact Amber (the precious stone) is fossilized rosin. Rosin was, and still is, applied to the horsehair of a fiddle bow to create more friction on the fiddle strings, as oldwood described. Rosin was also the earliest form of "hot melt" cement, often used on early rifleman's knives and even table cutlery to hold the knife tang in the hollow handle. When ground to a powder, it can be applied to almost any surface to increase its gripping power. Brownell's used to sell powdered rosin for this purpose... Maybe they still do.
I had not heard of putting pine tar on a breech plug, but I am not surprised. It would create a flexible, watertight and even gas-tight seal. Rosin is brittle, and I don't believe it would serve as well for this purpose as a dab of tar. I think Tallpine's observations are spot on. I have unbreeched several old guns, and recall they were generally not breeched nearly as tightly as now. Threads were often hand-filed and hand fitted, and rather coarse, although I have seen "thread plates" listed with gun smithing supplies sent to the posts on the frontier. I don't know if these were for cutting threads, like dies, or for checking threads, though.
Best regards,
Notchy Bob