I got my answer. Vinergroon rots leather.
Vinegarroon CAN rot leather if used
incorrectly, BUT there are still intact 18th century examples of what British Ordnance called "Blackened Leather" that were dyed with Vinegarroon and they considered "Blackened Leather" as "cheap leather goods" compared to Buff Leather.
This is why I asked if the Vinegarroon was applied to BOTH sides of the leather, I.E. the smooth and rough sides, because that is
NOT the correct way to do it.
The 18th century British specifications called for Vinegarroon to have ONLY been applied to the smooth side of the leather and the rough side NOT dyed. They knew if you applied it to the rough side, it would interfere with the necessary occasional working oil into the rough side of the leather to keep the fibers from breaking down and "rotting."
I hope Capt. Jas. will correct me if I'm wrong, but I think Eric Myall who was the Master of the Saddlers Shop at Colonial Williamsburg for many years, always WET the leather BEFORE applying Vinegarroon. If I'm correct, that helped ensure the Vinegarroon did not soak through into the middle of the leather. Eric also applied the Vinegarroon ONLY to the smooth side of the leather, per original 18th century techniques. After getting the desired dying results, Eric once again immersed leather into water and then worked oil into the rough side of the leather, because wet leather won't absorb TOO much oil. Off the top of my head, I don't remember if Eric used baking soda to neutralize the Vinegarroon, but I think he did and that was also done before he worked oil into the rough side of the leather.
I had already made the mistake of dying both sides of the leather with Fiebings dye in the 1980's one time, when I was going against tried-and-true leather dying techniques and thought to "speed up my dyeing" by just immersing a strap in the dye. THAT didn't work out well either, so I NEVER immersed an entire piece of leather in dye after that.
I can relate a mistake I made in the late 1990's that "rotted the leather" on my 18th century Waist Belt in ONLY Two Years when I was using Fiebings USMC Black Leather Dye instead of Vinegarroon, because I was not familiar with using Vinegarroon. This was also MY fault, BTW.
I was doing "Black Watch" then and unlike Regular British Soldiers who were normally issued Buff Leather Straps and often Waist Belts by their Commanding Officers; Scottish Soldiers stuck to the Issued "Cheap Blackened Leather" Straps and Waist Belts. OK, so I applied the Fiebings to the smooth side of the leather and admit I did dye the edges, but not the rough back side of the leather. Dyeing the edges didn't cause the problem, though.
I had read of period "Black Ball" that soldiers were issued to "dress" their blackened leather, but back then I didn't know how to make it. So, in an effort to keep the leather looking good, I used a modern dressing over the blackened smooth side of the leather. So far, so good. Had I stopped there, I would have been good.
THEN I got to thinking about my nice White Waist Coat we wore the Waist Belts over. I was concerned about oil from the Waist Belt staining my Waist
Coat. Now, THIS is where I screwed up! I decided to apply a layer of "Top Finish" over the ROUGH side of the leather to keep it from staining my Waist Coat. DUMB MOVE ON MY PART!!! That Top Finish Coat kept the rough leather side from being able to absorb the necessary occasional "maintenance" coats of oil to the leather. THAT caused the leather to crack/split right through the bend area of the leather Waist Belt in only two years, so I NEVER made that mistake again!
BTW, I have since learned to moisten the rough side of leather once or twice a year when I apply the "maintenance" coats of oil to the rough side of my leather goods. This helps ensure I don't apply too much oil to it. Then I allow it to dry thoroughly and hand buff it with a terry cloth rag, so there is little chance of the oil "bleeding out" onto my period clothing.
Gus