From what I know of it:
.535 balls seem to work a little better.
Tight loads seem to work a little better.
FFF seems to work a little better.
85 gr fff seems to be the sweet spot.
All that being said, don't run out and buy to much stuff and get all confused.
I would start with fff
I would start with .535 balls.
I would start with 70 gr fff
I would start with pre-lubed patches get some .010,some.015,some,020.
While you are buying your patches get some un-lubed ones of the same thickness and style.
Start off with 70 gr fff and a .010 patch.
Fire one fouling shot, then a 3 shot group @ 50 yds.
Run a a few patches through the bore and get it sort of clean.
Move up to 75 gr fff with the .010 patches and repeat the fouler and three shot groups.
Keep bumping up the powder till you get to 90gr or so.
Start again with the .015 patches.
Start again with the .020 patches.
Make sure you clearly mark your targets and see what load she likes the best.
After you compare targets, pick the best load and shoot your new gun for a month or two (DO NOT FILE YOUR SIGHTS).
After you run 100-200 balls through her, start the load development again and experiment with different types of lubes.
A pet load should poke it's head up soon enough.
After you get a base line of what shoots the best file the sights and make smoke.
You will never be done with experimenting with patches and lube, it's just part of the game.
I like to start a new gun off with the pre-lubed patches, just because of consistency - of dimension and amount of lube.
After I get a basic good load, I like to put a couple hundred rounds through it just to let everything settle in. Some times it takes a while.
If you are new to flintlocks, some folks need a little time to get used to the smoke and fire, some need a little time to get used to the hang time in firing, some need some time to get used to the different fit of the long rifle, most just need a little time to get used to the whole deal.
Get a fairly good load and shoot your rifle for a while. With the experience you learn from just shooting and loading your new rifle you can take that good load and tweak it into a great load.
You made an excellent choice in the .54. It will bring home the bacon large or small for many years to come.
You also have a new family here to help out if needed
Remember to take PICTURES !!!!
Good luck
Leo