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Caps: New or Old?

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I have an original old tin of Eley's pistol caps; the caps inside have tiny grooves vertically around the sides; are these the real old 19th C. caps, or something someone put there in more modern times? They're Copper. They seem so bright and fresh, but then being in a closed tin might have 'preserved' them. Thanks for any opinion.
 
I wouldn’t worry about the corrosion. With black powder you need to clean the piece anyway. I shot old imported CVA caps for years in the late 70s and early 80s with no harm to my old TC Hawken.
 
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