CDG: Yes Black powder makes its own oxygen, and can burn in a closed container that admits no additional oxygen. But that is only part of the story about how a flintlock fires.
I have to assume that you have seen blacksmiths using bellows to blow air on coals to increase the heat of the fire to forging temperatures. Now, that fire has all the oxygen it needs to burn from just the air above and around the coals. So, why do we have to ADD air to the fire? If your comment is the only relevant one, the answer would be that a bellows is a waste of time.
We know that is not true. Its also not true that adding air to the chamber in a flintlock is a waste of time.
Fire is a temperature sensitive form of oxidation. But she is a greedy lady, and loves more air. Give fire air, and she gets hotter, and hotter.
We can give fire more air several ways, but not in the barrel of a flintlock. We can suck the air in by creating a chimney that will use the column of rising hot air, to draw in more oxygen to the fire below. We can slant the sides of the chimney, like the top of a Cheyenne Style Tipi, so that as the warm air rises, it has to go through a smaller and smaller area, making it move faster, and creating a vacuum below that sucks in air to the fire. Both are passive systems that require no energy to pump air to the fire. We don't need bellows, or an oxygen tank, under pressure, to send oxygen to mix with a gase to produce hot fires.
And those methods won't work in a flintlock barrel, either. But they do work to produce a hotter fire.
The secret to igniting black powder in a flintlock barrel is to understand that like any fire, the chamber will burn the powder more quickly if there is More Oxygen in the barrel, the same as sucking it into a tipi, or chimney, or blowing it into the fire with a bellows. Since the breech of a flintlock is closed except for the vent hole, and we need that hole to be small to control escaping gases when the powder burns, we are kind of stuck on the ways to get more oxygen to that fire we want to build in the barrel.
My way is to use coarser powder( 2Fg instead of 3Fg) because the spaces between granules are larger and therefore hold more " free " oxygen. I do not recommend compressing the powder, as that would defeat the purpose of using the larger granule size of powder to gain more air. AND, I load the powder loose in the barrel, seating the ball on the powder but not crushing or compacting it in any way. That is done by marking the ramrod and always loading to the " mark ". Finally, I poke a hole in the powder charge pushing a vent pick through the touch hole before I prime the gun. This opens a hole in the powder to allow lots of granules to be ignited by the heat I generate from the flame from the flash powder being ignited next to the touch hole. That hole also provides that fire in my flash pan with some " free " oxygen, and being a greedy lady, the heat and flame go after that oxygen like a baby after warm mother's milk. Instead of igniting one or two granules of powder at the vent hole opening, and then waiting for the " fuse effect " to get the charge in the barrel burning, my way gets a lot of " fuses " going all at once. They in turn go after all that extra oxygen, and internal ignition time is shortened substantially.
I have had percussion rifle shooters come down the firing line to ask me if I had switched my fintlock for a percussion gun, because of how fast my flintlock goes off. When I show them I am shooting a flinter, they hang around to find out how I am able to get it to go off so fast, and watch the gun fire. ( kBOOM!, not F-f-f-sh-sh-sh-BOOM!)
I have had this discussion with other shooters, and even other long time flint shooters. Its not until they actually hear my gun go off that they begin to understand that my idea of " fast ignition " is a lot different than what they have accepted as " fast " ignition. When they try it my way, they go home much happier, and usually having shot much better scores.
Comparing velocities using the same amount of powder in a percussion gun of the same caliber, and comparing it to velocities of the same powder charge in a flintlock, the velocity in the flint gun will be less. You solve that by adding some more powder, rarely more than an additional 5-10 grains. In percussion guns, I recommend using 3Fg, and compressing the loads. The priming cap injects fire into the powder, and it fires the most consistently if you compact the powder. With flint guns, loose powder and lots of air seems to give the fastest ignition and the lowest SDV.
They are two Very Different Systems of Ignition, and the sooner shooters understand that, the easier they will find shooting flintlocks to be.
But, opinions differ. Have it your way. I use science as a tool; not as a brick wall that stops all further thought.I don't like just accepting " problems": I prefer to solve them. :hmm: