"But liquid water is not the same as humidity."
Kind of depends on where you live and hunt, how hot and Humid it is, or how "Wet" the air is during your hunt, DAN. On one deer hunt here in Champaign County, Illinois, we walked out to our stands in the dark, in Pea Soup FOG. That's as close to "Liquid Water" as you can get. Another deer hunt, in Southern Illinois, had me hunting in a drizzling rain most of the day. Water on everything, and pea soup in the pan after 10 minutes. Another hunt, on a Labor Day weekend in 1981, in Eastern TENNESSEE for wild boar saw us standing in fog, then mist, than light rain, then back to mist and fog and 80-90 degree temps all day long. Pea Soup in the pan within 10 minutes.; Perhaps the worst day I have hunted in was when it was below freezing with frozen ice all over the ground on my way to my stand in a tree. When the sun rose, a light breeze began to blow warm, MOIST air up from the South. It melted the ice around me, and sucked the moisture up into the air. It was like sitting in a cold shower, with moisture condensing on every piece of metal, which remained colder than the warmer air that ran over it. Pea Soup, with water condensing on,and dripping off the bottom of the frizzen into the pan of priming powder.
Yes, the pan was clean and dry before I primed it with 4Fg powder from my priming horn, kept tucked inside my shirt. The powder poured out of the horn just fine, all day long.
I learned ON MY OWN how to check and clean the priming powder out ever 15 minutes or so, and have no problem getting my flintlock to fire in these conditions.
Is that enough " Hands On " experience for you and your buddy? to satisfy you( he's hopeless)that I indeed know what I am talking about? ( rhetorical question requiring no response, thank you.)
I think most all flintlock shooters understand that its the powder RESIDUE that sucks up moisture from the air( Hydroscopic).
However, condensation on lock parts is also another source of "liquid water"( ? when is water not liquid?) that can foul flash pans. Direct contact by fog, mist, drizzles, etc. will also foul your priming powder, if you don't use some kind of "Cow's Knee" to cover the lock, and even then, when you have both high humidity and a substantial change in air temperature, you will still get condensation UNDER the cow's knee.(I've hunted with and without a cow's knee on my gun. I even tried wrapping the lock with plastic wrap to keep the pan and lock parts dry.)