You don't tell us the make of your gun barrel. There were .45 caliber barrels, made by Numerich Arms, that shot the small, .433" diameter ball.
So, Measure the bore diameter of your gun barrel.
Find a piece of solid brass rod, 3/8" in diameter, about a foot long to give it some weight. Then drop it down the unloaded barrel. Now take an oversized ball-say a .490 caliber--- and, after oiling your bore a lot, drive the ball into the muzzle of your barrel with a short starter and mallet. Drive it down until it begins to go down easier. That will tell you that you have a good sizing to the rifling grooves in the barrel.
Now, turn the barrel upside down, so that the muzzle is pointing at some soft surface- a pile of newspapers, old cushions, etc. Shake that brass rod up and down in the barrel to knock the ball back out of the barrel. The weight of the brass rod is enough to get this done, and the brass is soft enough that it won't damage your rifling.
With the slug now out of the barrel, you can measure the land to land diameter( bore diameter) with a micrometer. If you don't own one, any machine shop, or auto shop will. Just ask them to measure it for you. About 99% of the people who work in machine shops or auto shops are into guns, and they will be fascinated with your smokepole, and what you are trying to learn.
Once you know what the actual diameter of your bore is, ( the standard diameter NOW is .451") you can then determine if the prior owner was using too small a ball, and what size you can work with.
My brother has tried, .440", .445", .451", .454", & .457" balls in his ".45".
He's now using a .445" ball in his gun for shooting Chunk gun matches, but he had some surprising results with the larger diameter balls, on a few targets. They just proved to be not consistent, and he has gone back to the .445" balls.
Now, he is a target shooter, and has all the time in the world ( it seems) to load that ball in his barrel. If he were hunting, with that gun or his other .45, I can assure you that he would be shooting the .440" balls, at least for his follow up shots. :hatsoff: