The most common causes of misfires with percussion guns are the wrong size nipple/cap combination, and a poor alignment between the FACE of the hammer, and the top of the nipple. Worn nipples can cause the latter problem to show up after only a few shots.
Best advice is whenever you acquire a NEW-to- You percussion gun, Change the nipple for a new one.
Then, put some lipstick, or marking dye( lampblack works) on the top edge of the nipple. Lower the hammer to mark the face where it touches the top of the nipple. IF YOU DON'T see a full circle of dye on the face of the hammer( Inside the skirt) You need to grind off the part that is marked by the dye, retest, and regrind until you have a full ring showing on the face of the hammer.
With a full ring- indicates that your hammer is striking the cap completely onto the top of the nipple--- you will have positive ignition, PROVIDED, you use the correct sized caps for that nipple.
CAUTION: Nipples come in different diameters, and different heights above the shoulder, as well as different lengths of threads, and thread sizes. Most of us didn't know that, and thought if we got the thread Pitch correct, that was all we needed to replace our existing nipple. WRONG!
Most percussion rifles use a #11, Standard percussion cap. The "Magnum" caps were designed to ignite Substitute powders, which need the hotter caps, because the substitute powders burn at much higher temperatures than does Black Powder.
There are still replica muskets and military style rifles that come with a larger nipple, designed to use MUSKET caps. Musket caps are distinguished by the " WINGS " that flare off the end of them. They come in 4 and 6 wing styles, depending on manufacturer.
#10 percussion caps are intended to be used on most reproduction revolvers. Always ASK your dealer if the caps you are buying are correct for the model handgun you are shooting. There are many suppliers shown here under the Links section that are very helpful to callers with questions about percussion nipples, wrenches, caps, etc. for a particular model gun or action. Never hesitate to use their Toll Free phone numbers to ask them what they recommend you buy for your gun.
I personally agree with the recommendation to try the nipple wrenches made to remove revolver nipples. They are smaller in diameter and may be able to fit into the space provided in that "Wesson" lock to let you turn out the existing nipple. Break Free, and Liquid Wrench, along with simple Kerosene, can be used instead of KROIL, to dissolve the crud that might be holding a nipple in the bolster, letting you unscrew and remove it. There is also a newer product, called Evaporust, that may be available at Auto Zone Stores.