As many have said, BP has no dependency on external oxygen what-so-ever...it generates all that it needs...one only has to look at some obvious examples:
-BP cartridge shooters not only fill a shell casing with BP, but then compress it tightly, and then seal it with a seated bullet...no external oxygen, no air spaces between kernels, etc;
-Light a waterproof 'cherry bomb' or similar firecracker, toss into a bucket of water and see what happens;
-A GI hand grenade uses tightly packed BP and is completely sealed from the outside air;
I've seated Goex BP in caplocks, then Flintlocks for 20 years and I always lean heavily on the 2" ball of the range rod to compress it as tight as I possibly can until I literally hear that unique crunching/squeaking sound of black powder crushing under pressure, being transmitted back up the ramrod.
When the main charge lights off gas pressure is exerted in all directions, but the barrel confinement only allows pressure to travel in two directions:
1) Some minor exhaust gas/pressure starts blowing backwards out the vent;
2) The bulk of the pressure pushes forward against the underside of the projectile propelling it forward up bore;
Vacuum in the bore of a Flintlock ???
No. Gas pressure fills the bore...at greater pressure than the surrounding atmospheric pressure, "not less"...and that elevated pressure exists in the confined bore for the entire combustion cycle until the projectile exits the muzzle and allows the gas pressure to fully vent, at which time the bore pressure then equalizes back down to the surrounding atmospheric pressure.
I never cease to be amazed at the arm chair theories thrown out here over and over and over as if they're gospel...when they've been disproved over and over and over based upon hundreds of years of history, actual first hand experience by so many experienced BP members here, the recent modern scientific experiments, and common everyday examples of BP use all around.
BP doesn't need external oxygen to burn, it doesn't need 'air spaces' between the kernels, it doesn't need to be seated with less pressure in a Flintlock than a caplock, and it operate with a vacuum in the bore.
I may be completely wrong on all my points of course as I'm only operating on the basis of hands on experience. And by not operating on theories I may not understand these things...so please accept my apologies in advance for any incorrect statements I might have made.